Beilstein J. Org. Chem.2021,17, 630–670, doi:10.3762/bjoc.17.55
]PCBM; diazo compounds; mechanisms and optimal conditions of cyclopropanation; methanofullerenesC60; Introduction
Taking into consideration that all life on Earth is of organic origin. with carbon as its basic element (20% by weight of every living organism, and the fourth most abundant element in the
theoretically possible isomeric methanofullerenesC60.
Structures of monophenyldiazomethanes 28–30.
Structures of diphenyldiazomethanes 31–34.
Conjugates of benzocrown ethers with phenylmethanofullerenes 35–39.
Structures of para-phenylenebis(phenylfulleroid) 40 and meta-phenylenebis(phenylfulleroid) 41
.
Polysubstituted diphenylmethanofullerenes 169–177.
Fullerene-containing phenylacetylene dendrimers of the 1st and 2nd generation.
Dibenzosuberane-substituted fullerene derivatives 196 and 197.
Methods for the synthesis of methanofullerenesC60.
Synthesis of diphenyl-substituted fulleroids 1 and 2.
The reaction